ACIDITY AND CATALYTIC ACTIVITY OF ZIRCONIUM AND TITANIUM SULFATES HEAT-TREATED AT HIGH-TEMPERATURE - SOLID SUPERACID CATALYSTS

被引：90

作者：

ARATA, K

HINO, M

YAMAGATA, N

机构：

[1] IBARAKI COLL TECHNOL, KATSUTA 312, JAPAN

[2] HAKODATE TECH COLL, HAKODATE 042, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1990年 / 63卷 / 01期

关键词：

D O I：

10.1246/bcsj.63.244

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Acidity and catalytic activity of Zr(SO4)2 and Ti(SO4)2 calcined at 500-800°C were studied. The products obtained by calcination at 725°C for Zr(SO4)2 and at 625°C for Ti(SO4)2 showed the highest activity for the cracking of cumene among samples calcined at other temperatures; the former showed an acid strength of -13.16<H0≤-12.70 and the activity for the reaction of pentane.

引用

页码：244 / 246

页数：3

共 10 条

[1] FRIEDEL-CRAFTS REACTION IN HETEROGENEOUS SYSTEM .6. FRIEDEL-CRAFTS ISOPROPYLATION OF TOLUENE WITH ISOPROPYL HALIDES CATALYZED BY CALCINED IRON SULFATES SUBSTRATE AND POSITIONAL SELECTIVITY
ARATA, K
TOYOSHIMA, I
[J]. JOURNAL OF CATALYSIS, 1977, 47 (01) : 109 - 112
[2] ACIDITY AND CATALYTIC ACTIVITY OF IRON(II) SULFATE HEAT-TREATED AT HIGH-TEMPERATURE
ARATA, K
HINO, M
[J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1980, 53 (02) : 535 - 536
[3] CATALYTIC ACTIVITY OF IRON SULFATES FOR FRIEDEL-CRAFTS TYPE BENZYLATION OF TOLUENE WITH BENZYL-CHLORIDE
ARATA, K
SATO, K
TOYOSHIMA, I
[J]. JOURNAL OF CATALYSIS, 1976, 42 (02) : 221 - 226
[4] FRIEDEL-CRAFTS REACTION IN HETEROGENEOUS SYSTEM .5. FRIEDEL-CRAFTS BENZYLATION AND BENZOYLATION OF TOLUENE CATALYZED BY CALCINED IRON SULFATES
ARATA, K
YABE, K
TOYOSHIMA, I
[J]. JOURNAL OF CATALYSIS, 1976, 44 (03) : 385 - 391
[5] SOLID CATALYST TREATED WITH ANION .3. REACTION OF BUTANE TO ISOBUTANE CATALYZED BY IRON-OXIDE TREATED WITH SULFATE ION, SOLID SUPERACID CATALYST
HINO, M
ARATA, K
[J]. CHEMISTRY LETTERS, 1979, (10) : 1259 - 1260
[6] REACTIONS OF BUTANE AND ISOBUTANE CATALYZED BY TITANIUM-OXIDE TREATED WITH SULFATE ION - SOLID SUPERACID CATALYST
HINO, M
ARATA, K
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1979, (24) : 1148 - 1149
[7] SOLID CATALYST TREATED WITH ANION .2. REACTIONS OF BUTANE AND ISOBUTANE CATALYZED BY ZIRCONIUM-OXIDE TREATED WITH SULFATE ION - SOLID SUPERACID CATALYST
HINO, M
KOBAYASHI, S
ARATA, K
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (21) : 6439 - 6441
[8] SOLID CATALYSTS TREATED WITH ANIONS - SYNTHESIS OF SOLID SUPERACID CATALYST WITH ACID STRENGTH OF H0 LESS-THAN-OR-EQUAL-TO-16.04
HINO, M
ARATA, K
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1980, (18) : 851 - 852
[9] TANABE K, 1970, SOLID ACIDS BASES, P82
[10] Tanabe K., 1967, ADV CATAL, V17, P315

← 1 →