ELECTRON CONDUCTION IN ORGANIC SOLUTIONS

被引：34

作者：

NORTON, JD ^{[1
]}

ANDERSON, SA ^{[1
]}

WHITE, HS ^{[1
]}

机构：

[1] UNIV MINNESOTA,DEPT CHEM ENGN & MAT SCI,MINNEAPOLIS,MN 55455

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1992年 / 96卷 / 01期

关键词：

D O I：

10.1021/j100180a002

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A voltammetric study of electron conduction in nitrobenzene (NB)/toluene solutions is presented. Analysis of steady-state mass-transport-limited currents corresponding to the first and second one-electron reductions of NB (to the radical anion, NB-, and dianion, NB2-, respectively) indicates that electrogeneration of NB2- is suppressed to negligible values in concentrated NB solutions as a result of the increased flux of electrons away from the electrode surface via the self-exchange electron-transfer mechanism, NB- + NB half-arrow-right-over-half-arrow-left k(et) NB + NB-. Comparison of experimental and computer-simulated fluxes yields k(et) approximately 8.4 x 10(8) M-1 s-1. Current densities of magnitude greater than 0.5 A/cm2 can be attributed to the self-exchange electron-transfer reaction.

引用

页码：3 / 6

页数：4

共 33 条

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