EFFICIENCY OF SILICONE-GREASE-COATED DENUDERS FOR COLLECTION OF POLYNUCLEAR AROMATIC-HYDROCARBONS

被引:29
作者
COUTANT, RW [1 ]
CALLAHAN, PJ [1 ]
CHUANG, JC [1 ]
LEWIS, RG [1 ]
机构
[1] US EPA,RES TRIANGLE PK,NC 27711
来源
ATMOSPHERIC ENVIRONMENT PART A-GENERAL TOPICS | 1992年 / 26卷 / 15期
关键词
POLYCYCLIC AROMATIC HYDROCARBONS (PAH); SEMIVOLATILE ORGANIC COMPOUNDS; PHASE DISTRIBUTION; ANNUAL DENUDER;
D O I
10.1016/0960-1686(92)90020-L
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The overall efficiency of silicone-grease-coated denuders was determined for the collection of selected 3- and 4-ring polynuclear aromatic hydrocarbons (PAH). PAH studied were fluorene, phenanthrene, anthracene, acenaphthene and pyrene. Fluorene was subsequently eliminated from consideration because of analytical problems caused by the reactivity of this compound. Results are interpreted in terms of the collisional reaction efficiencies (gamma) for these compounds. An analysis of the effects of uncertainties in diffusion coefficients and gamma values for these compounds on overall phase distributions derived from experimental data suggests that the consequences of these uncertainties are less significant than normal variations due to sampling and analysis effects.
引用
收藏
页码:2831 / 2834
页数:4
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