THE REVISED STRUCTURE OF THE NORDITERPENOID ALKALOID PEREGRINE

被引：5

作者：

DELAFUENTE, G

RUIZMESIA, L

RODRIGUEZ, ML

机构：

[1] Centro de Productos Naturales Orgánicos 'Antonio González', CSIC-Universidad de La, Laguna

来源：

HELVETICA CHIMICA ACTA | 1994年 / 77卷 / 07期

关键词：

D O I：

10.1002/hlca.19940770708

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The structure of peregrine (1), a norditerpenoid alkaloid isolated from Delphunium peregrinum var. elongatum BOISS., was revised on the basis of the H-1-COSY, HMQC, HMBC, and ROESY NMR spectra and of the X-ray analysis of its parent alcohol 2. Some of the C-13-NMR resonances of 1 and the related alkaloids peregrine alcohol (2), 14-O-acetylperegrine (3), bicoloridine (4), bicoioridine alcohol (5), 6-O-acetylbicolorine (6), bicolonine (7), and 14-O-acelylbicolorine (8), were also reassigned.

引用

页码：1768 / 1772

页数：5

共 15 条

[1]

BAI Y, 1990, HETEROCYCLES, V31, P1233

[2] H-1 AND C-13 ASSIGNMENTS FROM SENSITIVITY-ENHANCED DETECTION OF HETERONUCLEAR MULTIPLE-BOND CONNECTIVITY BY 2D MULTIPLE QUANTUM NMR [J].