SUBSTITUTED (CARBAZOL-9-YL)(BENZOTRIAZOL-1-YL)METHANES - NOVEL ACYL ANION EQUIVALENTS

被引：42

作者：

KATRITZKY, AR

YANG, Z

LAM, JN

机构：

[1] Center for Heterocyclic Compounds, Department of Chemistry, University of Florida, Gainesville

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1991年 / 56卷 / 24期

关键词：

D O I：

10.1021/jo00024a039

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Alkyl(carbazol-9-yl)(benzotriazol-1-yl)methanes are deprotonated by BuLi to form anions which react with alkyl halides, aldehydes, and isocyanates to afford the expected products and which add 1,4 to alpha,beta-unsaturated ketones. These products are hydrolyzed by dilute acid at ambient temperature to afford the corresponding ketones.

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页码：6917 / 6923

页数：7

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