REACTION OF [(MU-H)OS3(CO)11]- ANION WITH DIOXYGEN

被引：10

作者：

CATHEY, CJ ^{[1
]}

JOHNSON, BFG ^{[1
]}

LEWIS, J ^{[1
]}

RAITHBY, PR ^{[1
]}

WONG, WT ^{[1
]}

机构：

[1] UNIV CAMBRIDGE,CHEM LAB,LENSFIELD RD,CAMBRIDGE CB2 1EW,ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 450卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(93)80171-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The anion [(mu-H)Os3(CO)11]- reacts with dioxygen in solution to give a yellow species which further reacts with Os6(CO)18 to yield [(A-H)Os3(CO)10 . (mu2-O2C) . Os6(CO)17] . The structure of the oxygen intermediate is proposed, and a mechanism of the reaction suggested.

引用

页码：C12 / C14

页数：3

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