CONVERSION OF AROMATIC KETONES, BENZYL ALCOHOLS, AND ALKYL ARYL ETHERS TO AROMATIC-HYDROCARBONS WITH LITHIUM 4,4'-DI-TERT-BUTYLBIPHENYL RADICAL-ANION

被引：12

作者：

KARAMAN, R ^{[1
]}

KOHLMAN, DT ^{[1
]}

FRY, JL ^{[1
]}

机构：

[1] UNIV TOLEDO, DEPT CHEM, BOWMAN ODDY LABS, TOLEDO, OH 43606 USA

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 43期

关键词：

D O I：

10.1016/S0040-4039(00)97012-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Treatment of tetrahydrofuran (THF) solutions of the title compounds with excess lithium (or potassium) metal under ultrasonic irradiation in the presence of catalytic amounts of the electron-transfer agent 4,4′-di-t-butylbiphenyl (DBB) caused conversions to aromatic hydrocarbons in good yields. Addition of 1 or 2 equiv of alkyl halides prior to aq ammonium chloride treatment during workup provided mono- or di-alkylated products. © 1990.

引用

页码：6155 / 6158

页数：4

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