THE EFFECT OF INORGANIC CONSTITUENTS OF THE SUPPORT ON THE CHARACTERISTICS OF CARBON-SUPPORTED PLATINUM CATALYSTS

被引:18
作者
RODRIGUEZREINOSO, F
MORENOCASTILLA, C
GUERRERORUIZ, A
RODRIGUEZRAMOS, I
LOPEZGONZALEZ, JD
机构
[1] UNIV NACL EDUC DISTANCIA, DEPT QUIM INORGAN, MADRID, SPAIN
[2] UNIV GRANADA, DEPT QUIM ORGAN, GRANADA, SPAIN
来源
APPLIED CATALYSIS | 1985年 / 15卷 / 02期
关键词
CARBON; -; Activated; CATALYSIS;
D O I
10.1016/S0166-9834(00)81843-6
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Two commercial activated carbons and the corresponding demineralized samples have been used as catalyst supports for platinum in order to learn about the role played by the inorganic constituents of the carbons on the catalyst characteristics. CO and H//2 chemisorption and X-ray line broadening have been used to determine metal dispersion and mean particle size. The results indicate that the inorganic matter on the carbon plays an important role in the stabilization of the average platinum particle size by making sintering more difficult.
引用
收藏
页码:293 / 300
页数:8
相关论文
共 12 条
[1]  
[Anonymous], 1975, STRUCTURE METALLIC C
[2]   HYDROGEN-OXYGEN TITRATION METHOD FOR MEASUREMENT OF SUPPORTED PLATINUM SURFACE AREAS [J].
BENSON, JE ;
BOUDART, M .
JOURNAL OF CATALYSIS, 1965, 4 (06) :704-&
[3]  
Cusumano J.A., 1978, CATALYSIS COAL CONVE
[4]  
DELECEA CS, 1979, THESIS U GRANADA
[5]  
Mahajan O. P., 1978, ANAL METHODS COAL CO, V1
[6]   CROSS-SECTIONAL AREAS OF MOLECULES ADSORBED ON SOLID SURFACES [J].
MCCLELLA.AL ;
HARNSBER.HF .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1967, 23 (04) :577-&
[7]  
Montgomery W. J., 1978, ANAL METHODS COAL CO, V1
[8]  
PALMER MB, 1980, J CHEM TECHNOL BIOT, V30, P205
[9]   ACTIVATED CARBONS FROM ALMOND SHELLS .2. CHARACTERIZATION OF THE PORE STRUCTURE [J].
RODRIGUEZREINOSO, F ;
LOPEZGONZALEZ, JD ;
BERENGUER, C .
CARBON, 1984, 22 (01) :13-18
[10]  
RODRIGUEZTEBAR A, 1984, MICROBIOL SCI, V1, P211