A STUDY OF THERMAL-DEGRADATION KINETICS OF H-H POLY(VINYLIDENE CHLORIDE)

被引：14

作者：

FARR, MP

HARRISON, IR

机构：

[1] Pennsylvania State Univ, University, Park, PA, USA, Pennsylvania State Univ, University Park, PA, USA

来源：

JOURNAL OF POLYMER SCIENCE PART C-POLYMER LETTERS | 1986年 / 24卷 / 06期

关键词：

CHEMICAL REACTIONS - Reaction Kinetics - POLYMERS - Molecular Structure;

D O I：

10.1002/pol.1986.140240604

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The structure of poly(vinylidene chloride)(PVDC) has been confirmed to be predominantly a head-to-tail configuration. Through novel synthesis routes the head-to-head (H-H) configuration of PVDC can be prepared. Although some preliminary work has been reported, the mechanism of thermal degradation of the H-H configuration is not well known. The purpose of this communication is to first, confirm the previous results and second, make a first attempt at understanding the thermal degradation of H-H PVDC.

引用

页码：257 / 261

页数：5

共 10 条

[1]

ANDERSON HC, 1964, J POLYM SCI B2, P115

[2] THERMAL-DECOMPOSITION OF POLY(VINYLIDENE CHLORIDE) IN SOLID-STATE [J].