THE CRYSTALLIZATION OF DIABASE GLASS

被引:37
作者
ZNIDARSICPONGRAC, V
KOLAR, D
机构
[1] J. Stefan Institute, E. Kardelj University, Ljubljana, 61000
关键词
D O I
10.1007/BF01130200
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The crystallization behaviour of diabase glass at elevated temperatures was studied in samples prepared by melting the diabase rock. DTA and X-ray analyses revealed the crystallization of diopside (CaO.MgO.2SiO2) at 865-degrees-C and anorthite (CaO.Al2O3.2SiO2) at 1060-degrees-C. Further, the kinetics of crystallization of diopside were studied. The phenomenological Johnson-Mehl-Avrami equation was used and the exponent n = 3/2 determined from the dependency of the volume fraction of the crystal phase (diopside) on time. The activation energy of crystallization of diabase glass 248 kJ mol-1 was estimated on the basis of DTA measurements carried out at different heating rates and found to be in good agreement with literature data for similar glass.
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页码:2490 / 2494
页数:5
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