SINGLE-STEP SELECTIVE OXIDATION OF PARA-CHLOROTOLUENE TO PARA-CHLOROBENZALDEHYDE OVER VANADIUM SILICATE MOLECULAR-SIEVES

被引：16

作者：

SELVAM, T ^{[1
]}

SINGH, AP ^{[1
]}

机构：

[1] NATL CHEM LAB,DIV CATALYSIS,POONA 411008,MAHARASHTRA,INDIA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 08期

关键词：

D O I：

10.1039/c39950000883

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Selective formation of para-chlorobenzaldehyde (> 65%) in a single step from para-chlorotoluene is reported for the first time using H2O2 as an oxidant and vanadium silicate molecular sieves as the catalyst.

引用

页码：883 / 884

页数：2

共 13 条

[1]

ABOUKAIS A, 1992, J PHYS CHEM-US, V96, P2617

[2]

Argauer R.J., 1972, U.S. Patent, Patent No. [3,702,886, 3702886]

[3]

BECK U, 1985, ULLMANNS ENCY IND A, V6, P897

[4] SILICALITE-2, A SILICA ANALOG OF THE ALUMINOSILICATE ZEOLITE ZSM-11 [J].

BIBBY, DM ;

MILESTONE, NB ;

ALDRIDGE, LP .

NATURE, 1979, 280 (5724) :664-665

[5]

BORGAONKAR HV, 1984, J CHEM TECH BIOT A, V34, P107

[6]

COSTANTINI M, 1989, STUD SURF SCI CATAL, V44, P159

[7]

RAO PRH, 1993, STUD SURF SCI CATAL, V76, P385

[8] STUDIES ON CRYSTALLINE MICROPOROUS VANADIUM SILICATES .2. FTIR, NMR, AND ESR SPECTROSCOPY AND CATALYTIC-OXIDATION OF ALKYLAROMATICS OVER VS-2 [J].

RAO, PRHP ;

BELHEKAR, AA ;

HEGDE, SG ;

RAMASWAMY, AV ;

RATNASAMY, P .

JOURNAL OF CATALYSIS, 1993, 141 (02) :595-603

[9] OXYFUNCTIONALIZATION OF ALKANES WITH H2O2 CATALYZED BY VANADIUM SILICATES [J].

RAO, PRHP ;

RAMASWAMY, AV .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (17) :1245-1246

[10] SYNTHESIS AND CHARACTERIZATION OF A LARGE PORE VANADIUM-CONTAINING MOLECULAR-SIEVE, V-NCL-1 [J].

REDDY, KR ;

RAMASWAMY, AV ;

RATNASAMY, P .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (21) :1613-1615

← 1 2 →