SYNTHESIS, X-RAY STRUCTURE AND REARRANGEMENT OF NITROGEN YLIDES OBTAINED UPON ALKYNE AND CO INSERTION REACTIONS INTO AMINOCARBENE COMPLEXES OF CHROMIUM

被引：15

作者：

RUDLER, H ^{[1
]}

PARLIER, A ^{[1
]}

GOUMONT, R ^{[1
]}

DARAN, JC ^{[1
]}

VAISSERMANN, J ^{[1
]}

机构：

[1] UNIV PARIS 06,CHIM MET TRANSIT LAB,F-75252 PARIS 05,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 16期

关键词：

D O I：

10.1039/c39910001075

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The aminocarbene complexes (CO)5Cr=C(R1)N(R2R3) 1 [R1 = H, Me, Ph, R2 = Me, R2R3 = (CH2)5, R3 = Me, cyclopropyl] react with diphenylacetylene to give nitrogen ylides 5 which were fully characterized by an X-ray analysis carried out on 5a [(CO)3CrR2R3N(C16H10OR1)-(R1 = H, R2 = R3 = (CH2)5] and which lead, upon nitrogen to carbon migrations of alkyl groups R2 and R3, to the expected lactams (e.g. 8 and 9) C16H10ONR1R2R3.

引用

页码：1075 / 1077

页数：3

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