INTERACTION OF CHLORINE WITH HYDROGENATED DIAMOND SURFACE

被引：35

作者：

ANDO, T

YAMAMOTO, K

SUEHARA, S

KAMO, M

SATE, Y

SHIMOSAKI, S

NISHITANIGAMO, M

机构：

[1] SUMITOMO SITIX CO, AMAGASAKI, HYOGO 660, JAPAN

[2] TOPPAN PRINTING CO LTD, SUGITO, SAITAMA 345, JAPAN

来源：

JOURNAL OF THE CHINESE CHEMICAL SOCIETY | 1995年 / 42卷 / 02期

关键词：

DIAMOND SURFACE; CHLORINE; CHEMICAL MODIFICATION; DIFFUSE REFLECTANCE FTIR; TPD; XPS;

D O I：

10.1002/jccs.199500039

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The interaction of chlorine with the hydrogenated diamond surface has been investigated by diffuse reflectance Fourier-transform Infrared (FTIR) spectroscopy, temperature-programmed desorption (TPD) spectroscopy, and X-ray photoelectron spectroscopy (XPS). The hydrogenated diamond surface is chlorinated by thermal reaction in chlorine. Hydrogen chemisorbed on the diamond surface is abstracted by chlorine and the chemisorption of chlorine is yielded. Hydroxyl groups are produced by treatment of the chlorinated diamond with water vapor at room temperature. Amino groups are produced by treatment of the chlorinated diamond with ammonia at 425 degrees C.

引用

页码：285 / 292

页数：8

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