SINGLET OXYGENATION OF OXADISILIRANES - SYNTHESES AND CRYSTAL-STRUCTURE OF 1,2,4,3,5-TRIOXADISILOLANES

被引：21

作者：

ANDO, W

KAKO, M

AKASAKA, T

KABE, Y

机构：

[1] Department of Chemistry, University of Tsukuba, Tsukuba, Ibaraki

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 29期

关键词：

D O I：

10.1016/S0040-4039(00)97575-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Singlet oxygenation of 2,2,3,3-tetraaryloxadisiliranes 1a-d gives the corresponding 1,2,4,3,5-trioxadisilolanes 2a-d, derivatives of a novel class of cyclic peroxides. The reaction mechanism is discussed in terms of possible peroxonium ion intermediate 6a as a nucleophilic oxidizing species. © 1990.

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页码：4177 / 4180

页数：4

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