CU[P(C6H5)3]2B6H9FE(CO)4 - RATIONAL SYNTHESIS OF A HETEROBIMETALLABORANE FROM B6H10

被引：13

作者：

BARTON, L

SRIVASTAVA, DK

机构：

[1] Department of Chemistry, University of Missouri-St. Louis, St. Louis

来源：

ORGANOMETALLICS | 1991年 / 10卷 / 08期

关键词：

D O I：

10.1021/om00054a083

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The heterobimetallaborane Cu[P(C6H5)3)]2B6-H9Fe(CO)4 is prepared by the reaction of K[Fe(CO)4B6H9] with [P(C6H5)3]2CuBr.0.5C6H6. The species forms by insertion of the Cu(I) moiety into a basal boron-boron bond in the Fe(CO)4B6H10 moiety generated by removal of a bridging hydrogen. This is the first report of a rational synthesis of a heterobimetallaborane from B6H10.

引用

页码：2982 / 2985

页数：4

共 48 条

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