ADSORPTION CHARACTERISTICS AND REACTIONS OF PROPYNE ON MICROPOROUS CRYSTALS

被引：5

作者：

MATSUMOTO, A

TSUTSUMI, K

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS | 1995年 / 91卷 / 11期

关键词：

D O I：

10.1039/ft9959101707

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The adsorption behaviour of propyne, which is a reactive alkyne, on proton and sodium-type Y-zeolites of different Si/Al ratios has been investigated by IR, EPR, GC/MS and adsorption calorimetry The propyne adsorptivity increased with increasing number of cation sites. The reactivity of adsorbed species depended strongly on the kind of cations. Propyne was chemisorbed on the proton-type zeolites, giving rise to several kinds of oligomers, whereas no chemisorption was observed on the sodium-type zeolite. The adsorbate-adsorbent interactions were evaluated by use of adsorption calorimetry.

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页码：1707 / 1713

页数：7

相关论文

共 40 条

[1]

Barrer R.M., 1978, ZEOLITES CLAY MINERA

[2] ZEOLITIC CARBON DIOXIDE - ENERGETICS AND EQUILIBRIA IN RELATION TO EXCHANGEABLE CATIONS IN FAUJASITE [J].

BARRER, RM ;

GIBBONS, RM .

TRANSACTIONS OF THE FARADAY SOCIETY, 1965, 61 (509P) :948-&

[3] SPECIFICITY IN PHYSICAL SORPTION [J].

BARRER, RM .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1966, 21 (04) :415-&

[4] MOLECULAR STATISTICAL CALCULATION OF THERMODYNAMIC ADSORPTION CHARACTERISTICS OF ZEOLITES USING ATOM-ATOM APPROXIMATION .1. ADSORPTION OF METHANE BY ZEOLITE NAX [J].

BEZUS, AG ;

KISELEV, AV ;

LOPATKIN, AA ;

DU, PQ .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS II, 1978, 74 :367-379

[5] ACETYLENE, METHYLACETYLENE AND ETHYLACETYLENE POLYMERIZATION ON H-ZSM5 - A SPECTROSCOPIC STUDY [J].

BORDIGA, S ;

RICCHIARDI, G ;

SPOTO, G ;

SCARANO, D ;

CARNELLI, L ;

ZECCHINA, A ;

AREAN, CO .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1993, 89 (11) :1843-1855

[6] ELECTRICALLY CONDUCTING ACETYLENE-METHYLACETYLENE CO-POLYMERS - SYNTHESIS AND PROPERTIES [J].

CHIEN, JCW ;

WNEK, GE ;

KARASZ, FE ;

HIRSCH, JA .

MACROMOLECULES, 1981, 14 (03) :479-485

[7] POLYMERIZATION OF METHYLACETYLENE IN HYDROGEN ZEOLITES [J].

COX, SD ;

STUCKY, GD .

JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (02) :710-720

[8]

Dubinin M.M., 1966, CHEM PHYS CARBON, P51

[9] FORMATION OF TRANS-POLYACETYLENE ON TRANSITION-METAL ZEOLITES - A RESONANCE RAMAN-STUDY [J].

DUTTA, PK ;

PURI, M .

JOURNAL OF CATALYSIS, 1988, 111 (02) :453-456

[10] HIGH-TEMPERATURE INFRARED SPECTROSCOPY OF OLEFINS ADSORBED ON FAUJASITES [J].

EBERLY, PE .

JOURNAL OF PHYSICAL CHEMISTRY, 1967, 71 (06) :1717-&

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