ENTANGLEMENT BETWEEN A POLYMERIC RING AND A ROD

被引:4
作者
KONIARIS, K
MUTHUKUMAR, M
机构
[1] UNIV MASSACHUSETTS,DEPT POLYMER SCI & ENGN,AMHERST,MA 01002
[2] UNIV MASSACHUSETTS,CTR MAT RES SCI & ENGN,AMHERST,MA 01002
[3] MIT,ARTIFICIAL INTELLIGENCE LAB,CAMBRIDGE,MA 02139
关键词
D O I
10.1063/1.470342
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Ring polymers are represented on a computer with the bead-stick model. If an infinitely thin spike is inserted at some (minimum) distance r from the center of mass of a Gaussian ring of contour length N, the probability P(r,N,w) of the ring winding a nonzero number of times w about the spike is nearly given by A exp[-(r/R(g))(2)/2 sigma(2)], where A and a depend on N and w, and R(g) is the radius of gyration of the polymer. We also find that the asymptotic results of related theoretical calculations cannot be realized in systems of practical size. (C) 1995 American Institute of Physics.
引用
收藏
页码:7136 / 7143
页数:8
相关论文
共 16 条
[1]   STATISTICAL MECHANICS OF ENTANGLED POLYMERS [J].
ALEXANDERKATZ, R ;
EDWARDS, SF .
JOURNAL OF PHYSICS PART A GENERAL, 1972, 5 (05) :674-+
[2]  
[Anonymous], 1986, INTRO PATH INTEGRAL
[3]  
[Anonymous], 1979, SCALING CONCEPTS POL
[4]  
[Anonymous], 1980, VISCOELASTIC PROPERT
[5]  
BAUMGARTNER A, 1984, MONTE CARLO METHODS
[6]   NEW POINTS-OF-VIEW IN KNOT-THEORY [J].
BIRMAN, JS .
BULLETIN OF THE AMERICAN MATHEMATICAL SOCIETY, 1993, 28 (02) :253-287
[8]  
Edwards R., 1968, J EXP MAR BIOL ECOL, V2, P15
[9]   STATISTICAL MECHANICS WITH TOPOLOGICAL CONSTRAINTS .I. [J].
EDWARDS, SF .
PROCEEDINGS OF THE PHYSICAL SOCIETY OF LONDON, 1967, 91 (573P) :513-&
[10]  
EDWARDS SF, 1982, P ROY SOC LOND A MAT, V385, P267