A CONVENIENT METHOD FOR FUNCTIONALIZATION OF THE 2-POSITION OF CYCLODEXTRINS

被引：170

作者：

RONG, D ^{[1
]}

DSOUZA, VT ^{[1
]}

机构：

[1] UNIV MISSOURI,DEPT CHEM,ST LOUIS,MO 63121

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 30期

关键词：

D O I：

10.1016/S0040-4039(00)97599-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new convenient strategy for functionalization of the 2-position of cyclodextrins involving deprotonation of cyclodextrin by sodium hydride followed by a nucleophilic attack of the resultant cyclodextrin oxyanion on the desired electrophile gives a high yield of the cyclodextrin derivative. © 1990.

引用

页码：4275 / 4278

页数：4

共 14 条

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[2] ARTIFICIAL ENZYMES
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[5] 6-POLYSUBSTITUTED ALPHA-CYCLODEXTRINS - APPLICATION OF KORNERS ABSOLUTE METHOD OF ISOMER DETERMINATION
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[6] SYNTHESIS OF MONOSUBSTITUTED CYCLOHEXAAMYLOSES
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[J]. CARBOHYDRATE RESEARCH, 1971, 18 (01) : 29 - +
[7] CHEMISTRY OF A HEPTANE-SOLUBLE CYCLODEXTRIN DERIVATIVE
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[J]. TETRAHEDRON LETTERS, 1985, 26 (03) : 267 - 270
[8] REGIOSELECTIVE SULFONATION OF A SECONDARY HYDROXYL GROUP OF CYCLODEXTRINS
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[J]. TETRAHEDRON LETTERS, 1987, 28 (03) : 321 - 324
[9] RENDLEMAN JA, 1973, ADV CHEM SER, V117, P54
[10] ROWLAND SP, 1971, CARBOHYD RES, V16, P243

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