MICELLIZATION OF AQUEOUS CATIONIC SURFACTANT SOLUTIONS AT THE MICELLAR STRUCTURE TRANSITION CONCENTRATION-BASED UPON THE CONCEPT OF THE PSEUDOPHASE SEPARATION

被引:48
作者
LEE, YS [1 ]
WOO, KW [1 ]
机构
[1] SEOUL NATL UNIV,COLL EDUC,DEPT CHEM EDUC,SEOUL 151742,SOUTH KOREA
关键词
D O I
10.1006/jcis.1995.1003
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Micellizations of aqueous solutions of cationic alkyltrimethylammonium bromide homologue series, i.e., dodecyltrimethylammonium bromide, tetradecyltrimethylammonium bromide, and hexadecyltrimethylammonium bromide, were described based upon the concept of the pseudophase separation. Surfactant parameters (s, y, and theta) were formulated by using our experimental NMR results. We suggest these parameters as the intrinsic properties which may characterize the micellization of aqueous C-n series in water. (C) 1995 Academic Press, Inc.
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页码:34 / 38
页数:5
相关论文
共 25 条
[1]  
[Anonymous], 1975, CATALYSIS MICELLAR M
[2]  
Bender M., 1991, INTERFACIAL PHENOMEN
[3]   MICELLIZATION OF IONIC SURFACTANTS - CALCULATIONS BASED ON A SELF-CONSISTENT FIELD LATTICE MODEL [J].
BOHMER, MR ;
KOOPAL, LK ;
LYKLEMA, J .
JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (23) :9569-9578
[4]  
CHUNG MI, 1975, J KOREAN CHEM SOC, V19, P398
[5]  
Delpuech, 1980, PRACTICAL NMR SPECTR
[6]  
Fendler J. H., 1982, MEMBRANE MIMETIC CHE
[7]   THEORY OF SELF-ASSEMBLY OF HYDROCARBON AMPHIPHILES INTO MICELLES AND BILAYERS [J].
ISRAELACHVILI, JN ;
MITCHELL, DJ ;
NINHAM, BW .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS II, 1976, 72 :1525-1568
[8]  
LEE KM, 1973, J KOREAN CHEM SOC, V17, P73
[9]  
LEE KM, 1980, J SCI ED SCI ED CENT, V5, P91
[10]  
LEE KM, 1976, J KOREAN CHEM SOC, V20, P193