NONCLASSICAL ORGANOLANTHANOID(II) COMPLEXES - SYNTHESIS AND REACTIVITY OF THE 1ST ORGANONEODYMIUM(II) COMPOUND

被引：28

作者：

WEDLER, M ^{[1
]}

RECKNAGEL, A ^{[1
]}

EDELMANN, FT ^{[1
]}

机构：

[1] UNIV GOTTINGEN,INST ANORGAN CHEM,TAMMANNSTR 4,W-3400 GOTTINGEN,GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 395卷 / 02期

关键词：

D O I：

10.1016/0022-328X(90)85283-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

NdCl2(THF)2 reacts with KCp{black star} to give [K(THF)n]2[Cp2{black star}NdCl2] (1) which represents the first divalent organoneodymium complex. Treatment of 1 with tBuCl, [Me2NC(S)S]2 or MesSeSeMes affords the organoneodymium(III) complexes Cp2{black star}NdCl(THF) (2), Cp2{black star}Nd(S2CNMe2) (3) and Cp2{black star}NdSeMes(THF) (4) (Cp{black star} = η5- pentamethylcyclopentadienyl). © 1990.

引用

页码：C26 / C29

页数：4

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