ALKYLATION OF 2,6-DIPHENYLPYRYLIUM AND 2,6-DI-T-BUTYLPYRYLIUM IONS BY PHOTOCHEMICAL-REACTION WITH TETRAALKYLSTANNANES

被引:7
作者
BACIOCCHI, E
DODDI, G
IOELE, M
ERCOLANI, G
机构
[1] UNIV ROMA LA SAPIENZA,CNR,CTR STUDIO MECCANISMI REAZ,I-00185 ROME,ITALY
[2] UNIV CATANIA,IST CHIM AGR,I-95123 CATANIA,ITALY
关键词
D O I
10.1016/S0040-4020(01)90231-5
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
2,6-diphenylpyrylium and 2,6-di-t-butylpyrylium perchlorates are easily converted into a number of the corresponding 4-alkyl derivatives by photochemical reaction with tetraalkylstannanes, in MeCN at room temperature. The mechanism of the process is discussed.
引用
收藏
页码:3793 / 3800
页数:8
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