K-OC ESTIMATION OF DEETHYLATRAZINE, DEISOPROPYLATRAZINE, HEXAZINONE AND TERBUTHYLAZINE BY REVERSED-PHASE CHROMATOGRAPHY AND SORPTION ISOTHERMS

被引:22
作者
DONATI, L [1 ]
KEIZER, J [1 ]
BOTTONI, P [1 ]
SCENATI, R [1 ]
FUNARI, E [1 ]
机构
[1] IST SUPER SANITA,IGIENE AMBIENTALE LAB,I-00166 ROME,ITALY
关键词
K-D; K-OC; HPLC; TRIAZINES;
D O I
10.1080/02772249409358038
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The K-OC of three triazine herbicides (atrazine, hexazinone and terbuthylazine) and two triazine degradation products (deethylatrazine and deisopropylatrazine) were derived both by using a HPLC-reversed phase chromatography method and measuring the K-D with sorption isotherms. 21 reference substances and 3 different chromatographic conditions were used to measure the K-OC with the HPLC method. The K-OC values from sorption isotherms were determined using 6 different soils. The two different K-OC values for atrazine, deethylatrazine, deisopropylatrazine and hexazinone derived from the two methods were similar, while those of terbuthylazine were more different. Deethylatrazine, deisopropylatrazine and hexazinone had very low K-OC values, even lower than that of atrazine, and this indicates their tendency to move through the soil
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页码:1 / 10
页数:10
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