A NEUTRON-SCATTERING STUDY OF THE STRUCTURE OF SUPERCRITICAL CARBON-DIOXIDE

被引:44
作者
ISHII, R
OKAZAKI, S
OKADA, I
FURUSAKA, M
WATANABE, N
MISAWA, M
FUKUNAGA, T
机构
[1] TOKYO INST TECHNOL, DEPT ELECTR CHEM, MIDORI KU, YOKOHAMA, KANAGAWA 227, JAPAN
[2] NATL LAB HIGH ENERGY PHYS, TSUKUBA, IBARAKI 305, JAPAN
[3] NIIGATA UNIV, FAC SCI, DEPT CHEM, NIIGATA 95021, JAPAN
[4] NAGOYA UNIV, DEPT CRYSTALLINE MAT SCI, CHIKUSA KU, NAGOYA, AICHI 464, JAPAN
基金
日本学术振兴会;
关键词
D O I
10.1016/0009-2614(95)00519-A
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The structure factor S(Q) of supercritical carbon dioxide has been measured over a wide range of the scattering vector Q (0.018-30 Angstrom(-1)) using two neutron apparatuses. The measured S(Q) has been Fourier transformed into the neutron weighted radial distribution function, G(N)(r). This measurement enables us to analyze the short-range and long-range structures simultaneously in the supercritical fluid.
引用
收藏
页码:84 / 88
页数:5
相关论文
共 17 条
[1]  
Adya, Wormald, First direct observation of orientationally correlated molecules in CO2(l) by neutron diffraction, Molecular Physics, 74, (1991)
[2]  
Bausenwein, Bertagnolli, Gutwerk, Todheide, Chieux, The structure of fluid carbon dioxide by neutron diffraction at high pressure and by RISM calculations, Molecular Physics, 76, (1992)
[3]  
Londono, Shah, Wignall, Cochran, Bienkowski, J. Chem. Phys., 99, (1993)
[4]  
Postorino, Tromp, Ricci, Soper, Neilson, Nature, 366, (1993)
[5]  
Buontempo, Postorino, Ricci, Soper, Neutron diffraction study of heavy water steam, Molecular Physics, 81, (1994)
[6]  
Strauss, Zweier, Bertagnolli, Bausenwein, Todheide, Chieux, J. Chem. Phys., 101, (1994)
[7]  
Bausenwein, Bertagnolli, David, Goller, Zweier, Todheide, Chieux, J. Chem. Phys., 101, (1994)
[8]  
Tromp, Postorino, Neilson, Ricci, Soper, J. Chem. Phys., 101, (1994)
[9]  
Nishikawa, Takematsu, Chem. Phys. Letters, 226, (1994)
[10]  
Paalman, Pings, J. Appl. Phys., 33, (1962)