SYNTHESIS OF C-GLYCOFURANOSIDES BY THE STEREOSELECTIVE REDUCTION OF HEMIACETALS

被引：26

作者：

CALZADA, E ^{[1
]}

CLARKE, CA ^{[1
]}

ROUSSINBOUCHARD, C ^{[1
]}

WIGHTMAN, RH ^{[1
]}

机构：

[1] HERIOT WATT UNIV,DEPT CHEM,EDINBURGH EH14 4AS,MIDLOTHIAN,SCOTLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1995年 / 05期

关键词：

D O I：

10.1039/p19950000517

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reaction of protected glycofuranolactones with organolithium reagents and reduction of the resultant hemiacetals with triethylsilane-boron trifluoride gives a stereocontrolled route to C-glycofuranosides, with hydride delivery occurring cis- to an adjacent oxygen function.

引用

页码：517 / 518

页数：2

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