SYNTHESIS, STRUCTURE, AND REACTIVITY OF RU(ETA6-C6ME6)[ETA4-C6ME4(CH)2] - AN UNUSUAL TRANSITION-METAL ORTO-XYLYLENE COMPLEX

被引：45

作者：

HULL, JW ^{[1
]}

GLADFELTER, WL ^{[1
]}

机构：

[1] UNIV MINNESOTA,DEPT CHEM,MINNEAPOLIS,MN 55455

来源：

ORGANOMETALLICS | 1982年 / 1卷 / 12期

关键词：

D O I：

10.1021/om00072a033

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

引用

页码：1716 / 1718

页数：3

共 11 条

[1] ORGANO-METALLIC ELECTRON RESERVOIRS .5. A NOVEL MODE OF C-H ACTIVATION USING DIOXYGEN VIA SUPEROXIDE RADICAL-ANION IN SOLUTION AND IN THE SOLID-STATE WITH C5R5FEIC6R' 6 - SUBSEQUENT BOND FORMATION WITH C, SI, P, MN, FE, CR, MO, AND HALOGENS
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[2] REVERSIBLE DOUBLE DEPROTONATION OF HEXAMETHYLBENZENE ON RUTHENIUM - FORMATION OF A FLUXIONAL ETA-3-BENZYL COMPOUND BY PROTONATION OF AN ORTHO-QUINODIMETHANE COMPLEX OF RUTHENIUM(0)
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[3] FACILE DELTA-HYDROGEN ABSTRACTION FROM A RUTHENIUM COMPLEX - POSSIBLE 1 4-ETA-BONDING OF THE ORTHO-XYLYLENE LIGAND
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[4] PLATINACYCLOPENTENE FORMATION VIA DELTA-HYDROGEN ABSTRACTION
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[5] SYNTHESIS AND REACTIONS OF A DIMETALLACYCLOHEXENE - THERMAL-CONVERSION TO AN ORTHO-XYLYLENE COMPLEX AND PHOSPHINE-INDUCED CONVERSION TO FREE ORTHO-XYLYLENE AND A NEW REACTIVE DINUCLEAR COBALT COMPLEX
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[6] METAL-COMPLEXES DERIVED FROM THE ORTHO-XYLYLIDENE LIGAND, ORTHO-C6H4(CH2-)2, AND THE X-RAY CRYSTAL AND MOLECULAR-STRUCTURE OF THE METALLOCYCLE [ZR(ETA-C5H5)2[(CH2)2C6H4-ORTHO]]
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[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1980, (11) : 476 - 477
[7] SYNTHESIS AND STRUCTURE OF THE NB-IV METALLOCYCLES [M(ETA-C5H4SIME3)2[CH2C6H4CH2-O]] (M=NB, R=ME3SI) AND REDUCTIVE CLEAVAGE OF D0 ANALOGS (M=TI, ZR, OR HF, R=H OR ME3SI) BY NA[C10H8]
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[8] A METALLOTRICYCLE - SYNTHESIS, ONE-ELECTRON REDUCTION, AND CRYSTAL-STRUCTURE OF THE THERMALLY ROBUST COMPLEX TRIS-ORTHO-XYLIDENETUNGSTEN(VI), [W(CH2C6H4CH2-ORTHO)3]
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[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1981, (10) : 485 - 486
[9] SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF A WV METALLOCYCLE [(W(CH2C6H4CH2-O)2O)2MG(TETRAHYDROFURAN)4]
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[10] ROLE OF CYCLOBUTADIENEIRON TRICARBONYL IN CYCLOBUTADIENE PROBLEM
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[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1975, 100 (01) : 205 - 217

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