ARSENIC COMPOUNDS IN THE EDIBLE RED ALGA, PORPHYRA-TENERA, AND IN NORI AND YAKINORI, FOOD ITEMS PRODUCED FROM RED ALGAE

被引：42

作者：

SHIBATA, Y

JIN, K

MORITA, M

机构：

[1] National Institute for Environmental Studies, Tsukuba, 305

[2] Hokkaido Institute of Public Health, Sapporo, Hokkaido, 060, Kita 19–Nishi 12, Kitaku

来源：

APPLIED ORGANOMETALLIC CHEMISTRY | 1990年 / 4卷 / 03期

关键词：

Arsenic‐containing ribofuranosides; arsenosugars; high‐performance liquid chromatography; hydride generation–atomic absorption spectrometry; inductively coupled plasma mass spectrometry; methylarsenate compounds; nori; Porphyra tenera; red alga; yakinori;

D O I：

10.1002/aoc.590040313

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Arsenic compounds were extracted with methanol/water (1:1, v/v) from freeze‐dried samples of the edible red alga, Porphyra tenera (asakusanori in Japanese), and also from nori and yakinori, food items produced from red algae. The extracts were analyzed by high‐performance liquid chromatography (HPLC) with an inductively coupled plasma mass spectrometer (ICPMS) serving as an arsenic‐specific detector. Two arsenic‐containing ribofuranosides were identified in all samples tigated, and they accounted for almost all the extractable arsenic (8.7–21 mg As Kg−1 dry sample) in each sample. A compound bearing a glycer‐ophosphoryl glycerol moiety was dominant in every sample. Arsenite, arsenate, methylarsonate, and dimethylarsinate were quantified by hydride generation and atomic absorption spectrometry. Arsenate and dimethylarsinate were detected in all samples at low levels (around 0.15 and 0.05 mg As Kg−1 dry sample, respectively). Arsenite was detected only in the unprocessed Porphyra tenera at 0.005 mg As Kg−1 dry sample. Methylarsonate was not found in any of the samples. Copyright © 1990 John Wiley & Sons Ltd.

引用

页码：255 / 260

页数：6

共 25 条

[1]

Edmonds JS, Francesconi KA, Cannon JR, Raston CL, Skelton BW, White AH, (1977)

[2]

(1987)

[3]

Hanaoka K, Yamamoto H, Kawashima K, Tagawa S, Kaise T, Ubiquity of arsenobetaine in marine animals and degradation of arsenobetaine by sedimentary micro-organisms, Applied Organometallic Chemistry, 2, (1988)

[4]

Morita M, Shibata Y, Speciation of arsenic compounds in marine life by high performance liquid chromatography combined with inductively coupled argon plasma atomic emission spectrometry., Analytical Sciences, 3, (1987)

[5]

Edmonds JS, Francesconi KA, Nature (London), 289, (1981)

[6]

Edmonds JS, Francesconi KA, (1983)

[7]

Edmonds JS, Francesconi KA, Healy PC, White AH, (1982)

[8]

Shibata Y, Morita M, Edmonds JS, Purification and identification of arsenic-containing ribofuranosides from the edible brown seaweed, Laminaria japonica (MAKONBU), Agricultural and Biological Chemistry, 51, (1987)

[9]

Edmonds JS, Morita M, Shibata Y, (1987)

[10]

Shibata Y, Morita M, Agric. Biol. Chem., 52, (1988)

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