UNUSUAL MAGNETIC AND STRUCTURAL ONE-DIMENSIONAL NICKEL(II) AZIDO SYSTEMS

被引：54

作者：

ESCUER, A ^{[1
]}

VICENTE, R ^{[1
]}

ELFALLAH, MS ^{[1
]}

RIBAS, J ^{[1
]}

SOLANS, X ^{[1
]}

FONTBARDIA, M ^{[1
]}

机构：

[1] UNIV BARCELONA,DEPT CRISTALLOG & MINERAL,E-08028 BARCELONA,SPAIN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1993年 / 19期

关键词：

D O I：

10.1039/dt9930002975

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complexes of general formula (Ni(L)(N3)][ClO4] (L is meso-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane or 2,3-dimethyl-1,4,8,11-tetraazacyclotetradeca-1,3-diene), have been characterized by X-ray crystallography; both are chains in which the nickel(II)-tetraammine fragment is bridged by one mu-azido ligand in trans arrangement, showing unusual magnetic and/or crystallographic properties; preliminary magnetic susceptibility data indicate strong antiferromagnetic coupling.

引用

页码：2975 / 2976

页数：2

共 5 条

[1]

BORRAS JJ, 1991, THESIS U VALENCIA SP

[2]

Carlin R. L., 1986, MAGNETOCHEMISTRY

[3] 2 NEW MU-AZIDO NICKEL(II) UNIFORM CHAINS - SYNTHESES, STRUCTURES, AND MAGNETOSTRUCTURAL CORRELATIONS [J].

ESCUER, A ;

VICENTE, R ;

RIBAS, J ;

ELFALLAH, MS ;

SOLANS, X ;

FONTBARDIA, M .

INORGANIC CHEMISTRY, 1993, 32 (17) :3727-3732

[4] THE 1ST 1D NICKEL(II) COMPLEX WITH A SINGLE AZIDO BRIDGE - STRUCTURE AND MAGNETIC-BEHAVIOR OF CATENA-(MU-N3)[NI(1,4,8,11-TETRAAZACYCLOTETRA-DECANE)](CLO4)H2O [J].

ESCUER, A ;

VICENTE, R ;

RIBAS, J ;

ELFALLAH, MS ;

SOLANS, X .

INORGANIC CHEMISTRY, 1993, 32 (06) :1033-1035

[5]

WENG CY, 1968, THESIS CARNEGIE I TE

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