HIGH-YIELD FORMATION OF [(MO(III)4S4)(H2O)12](4+) BY REACTION OF [(MO(IV)3S4)(H2O)(9)](4+) WITH METALLIC LEAD

被引：6

作者：

BRORSON, M ^{[1
]}

HYLDTOFT, J ^{[1
]}

JACOBSEN, CJH ^{[1
]}

OLESEN, KG ^{[1
]}

机构：

[1] HALDOR TOPSOE RES LABS,HALDOR TOPSOE RES LABS,DK-2800 LYNGBY,DENMARK

来源：

INORGANICA CHIMICA ACTA | 1995年 / 232卷 / 1-2期

关键词：

MOLYBDENUM COMPLEXES; SULFIDE COMPLEXES; CLUSTER COMPLEXES; CUBANE-LIKE COMPLEXES;

D O I：

10.1016/0020-1693(94)04356-Z

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Anaerobic reaction in 2 M hydrochloric acid of the incomplete cubane-like molybdenum(IV) cluster aqua ion, [Mo3S4(H2O)(9)](4+), with metallic lead gave a 80% yield of the complete cubane-like molybdenum(III) cluster aqua ion, [Mo4S4(H2O)(12)](4+). As a preparative route to [Mo4S4(H2O)(12)](4+) this reaction is more convenient than those previously reported. The conversion of the Mo-3(IV) cluster to the Mo-4(III) cluster involves a breakdown of [Mo3S4](4+) units under the reductive influence of metallic lead.

引用

页码：171 / 173

页数：3

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