Measurement of the low-frequency shear modulus of polymeric liquids

被引:1
作者
Derjaguin, BV
Badmaev, BB
Bazaron, UB
Lamazhapova, KD
Budaev, OR
机构
[1] RUSSIAN ACAD SCI,INST NAT SCI,BURYAT SCI CTR,ULAN UDE,RUSSIA
[2] RUSSIAN ACAD SCI,INST PHYS CHEM,MOSCOW 117915,RUSSIA
关键词
relaxation; complex shear modulus;
D O I
10.1080/00319109508031637
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The present work describes the resonance method for measurement of a low-frequency (about 10(5) Hz) complex shear modulus of liquids by the use of a piezoquartz crystal. The problem of interaction of an oscillating system of the type piezoquartz-liquid interlayer-cover plate is analyzed. From the analysis of the problem there follow three methods for measuring the elasticity modulus of liquids. The investigation results of a homologous series of polymethyl siloxane liquids are presented. It has been shown that as the molecular weight of the series being investigated increases, the elasticity modulus value also increases, while the mechanical losses angle tangent passes through its maximum.
引用
收藏
页码:201 / 209
页数:9
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