PREFERENTIAL ATTACK OF THE TERMINAL HYDROGEN IN (MU-H)OS3(CO)11H BY THE (CF3)2NO RADICAL AND X-RAY STRUCTURE OF ((MU-H)OS3(CO)11)[ON(CF3)2]

被引：3

作者：

ANG, HG ^{[1
]}

KWIK, WL ^{[1
]}

KOH, CH ^{[1
]}

LEONG, WK ^{[1
]}

JOHNSON, BFG ^{[1
]}

LEWIS, J ^{[1
]}

RAITHBY, PR ^{[1
]}

机构：

[1] UNIV CAMBRIDGE,CHEM LAB,CAMBRIDGE CB2 1EW,ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 420卷 / 02期

关键词：

D O I：

10.1016/0022-328X(91)80269-P

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Bis(trifluoromethyl)nitroxyl radical, (CF3)2NO, has been shown to preferentially attack the terminal hydrogen from the (mu-H)OS3(CO)11H cluster to give the derivative (mu-H)OS3(CO)11[(CF3)2NO)] 1 together with bis(trifluoromethyl)hydroxylamine in quantitative yields. A radical mechanism is proposed. The product 1 represents the first example of a stable metal carbonyl cluster containing the perfluoro (CF3)2NO radical, a relatively strong oxidant. The X-ray structure and IR spectra are reported.

引用

页码：289 / 292

页数：4

共 7 条

[1]

ANG HG, 1968, J CHEM SOC CHEM COMM, P1320

[2] REACTIONS INVOLVING TRANSITION-METALS .16. RHODIUM, IRIDIUM, PLATINUM, AND GOLD COMPLEXES CONTAINING THE BIS(TRIFLUOROMETHYL)-AMINO-OXY-LIGAND [J].