REACTION OF 1,2-BORYLPHOSPHINOETHENE WITH PHENYL ISOCYANATE AND THE STRUCTURE OF THE REACTION-PRODUCTS

被引：9

作者：

ARBUZOV, BA

NIKONOV, GN

BALUEVA, AS

KAMALOV, RM

PUDOVIK, MA

SHAGIDULLIN, RR

PLYAMOVATYI, AK

KHADIULLIN, RS

机构：

[1] A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Branch

来源：

BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE | 1991年 / 40卷 / 10期

关键词：

D O I：

10.1007/BF00963514

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of 1-butyl-1-dibutylboryl-2-phenyl-2-phenylphosphinoethene with phenyl isocyanate gave two structural isomers, which were identified as 1-aza-5-phosphonia-2-borata-3-cyclohexene and 2-aza-4-phosphonia-1-boratabicyclo-[3.1.0]hexane by P-31 NMR and IR spectroscopy and x-ray diffraction structural analysis. The reversibility of the interconversion of these isomers was demonstrated. The reversible migration of a butyl anion from a carbon atom to the boron atom during this process was found.

引用

页码：2099 / 2102

页数：4

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