PRECURSORS OF HALOGENATED GERMENES

被引：3

作者：

ANSELME, G

COURET, C

ESCUDIE, J

SATGE, J

机构：

[1] Laboratoire de Chimie des Organominéraux, URA 477, Université P. Sabatier, 31062, Toulouse cedex

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 1991年 / 21卷 / 02期

关键词：

D O I：

10.1080/15533179108020178

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New germanes, the mesityfluorenyl- or difluorenyldimethoxygermanes 3c and 4c, have been prepared from mesityltrimethoxygermane or dichlorodimethoxygermane respectively and fluorenyllithium or -sodium. Further addition of hydrochloric or hydrofluoric acid affords the corresponding dichloro- or difluorogermanes 3a,b and 4a,b. Such derivatives are potential precursors of halogenated germenes.

引用

页码：229 / 237

页数：9

共 15 条

[1]

ALISON GE, 1990, J AM CHEM SOC, V112, P1672

[2]

ANSELME G, UNPUB

[3] MULTIPLY BONDED GERMANIUM SPECIES - RECENT DEVELOPMENTS [J].

BARRAU, J ;

ESCUDIE, J ;

SATGE, J .

CHEMICAL REVIEWS, 1990, 90 (01) :283-319

[4] GERMANIUM ESTERS .1. PARACHORS AND MOLECULAR STRUCTURE [J].

BRADLEY, DC ;

KAY, LJ ;

WARDLAW, W .

JOURNAL OF THE CHEMICAL SOCIETY, 1956, (DEC) :4916-4926

[5] THE 1ST STABLE GERMENE - A COMPOUND WITH A GERMANIUM CARBON DOUBLE-BOND [J].

COURET, C ;

ESCUDIE, J ;

SATGE, J ;

LAZRAQ, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (14) :4411-4412

[6]

Knoll F., 1989, ADV INORG CHEM, V33, P259

[7]

LAZRAQ M, UNPUB

[8] PHOSPHAALKYNES AND PHOSPHAALKENES [J].

MARKOVSKI, LN ;

ROMANENKO, VD .

TETRAHEDRON, 1989, 45 (19) :6019-6090

[9] STABLE GERMAETHENES [J].

MEYER, H ;

BAUM, G ;

MASSA, W ;

BERNDT, A .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1987, 26 (08) :798-799

[10] MULTIPLE BONDING TO SILICON [J].

RAABE, G ;

MICHL, J .

CHEMICAL REVIEWS, 1985, 85 (05) :419-509

← 1 2 →