[(CO)3(PPH3)2OSAG(O2CCF3)] - A MODEL FOR AN INTERMEDIATE ON THE REACTION COORDINATE IN ELECTRON-TRANSFER

被引：37

作者：

SONG, L ^{[1
]}

TROGLER, WC ^{[1
]}

机构：

[1] UNIV CALIF SAN DIEGO,DEPT CHEM,9500 GILMAN DR,LA JOLLA,CA 92093

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1992年 / 31卷 / 06期

关键词：

D O I：

10.1002/anie.199207701

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The formation of a complex with an osmium-silver bond precedes the actual electron transfer Os --> Ag in the oxidation of trans-[Os(CO3(PPh3)2)] with Ag(O2CCF3) as indicated by the results of electrochemical measurements and the X-ray structure analysis of the title complex depicted below (the phenyl groups of the phosphine ligands are not shown). This complex can thus be considered a model for intermediates in the oxidation of organometallic compounds by Ag+.

引用

页码：770 / 772

页数：3

共 22 条

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