TETRAHYDROFURAN-PODANDS, STEREOSELECTIVE SYNTHESIS OF TRANS-2,5-OLIGO-TETRAHYDROFURANS

被引：32

作者：

KOERT, U

STEIN, M

HARMS, K

机构：

[1] Fachbereich Chemie der Philipps Universität, 3550 Marburg, Hans-Meerwien-straße

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 14期

关键词：

D O I：

10.1016/S0040-4039(00)77598-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Enantiomerically pure THF-podands 1 were synthesized along a linear route starting from lactone 3. A high degree of stereochemical control was achieved by chelation controlled addition of the functionalized Grignard reagent 7 to alpha-alkoxy-aldehydes of type 6.

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页码：2299 / 2302

页数：4

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