MATRIX REACTION OF THE OXYGEN ATOM WITH THE CBRCL3 MOLECULE - IDENTIFICATION OF PHOSGENE COMPLEXES WITH CL-2 AND BR-2

被引：14

作者：

ABDELAOUI, O ^{[1
]}

SCHRIVER, L ^{[1
]}

SCHRIVER, A ^{[1
]}

机构：

[1] UNIV PARIS 06,PHYS MOLEC & ATMOSPHER LAB,CNRS,UPR 136,TOUR 13,BTE 76 4 PL JUSSIEU,F-75252 PARIS 05,FRANCE

来源：

JOURNAL OF MOLECULAR STRUCTURE | 1992年 / 268卷 / 04期

关键词：

D O I：

10.1016/0022-2860(92)80220-C

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

FT-IR spectroscopy has been coupled with the matrix isolation technique to investigate the mechanism of the CBrCl3 photooxidation by ozone at 12 K by UV light. COCl2 is observed as the only primary product and CO as a secondary photolysis product. A 35 K warm up after photolysis generated phosgene complexes with Cl2 and Br2. Identification of these molecular complexes was performed with mixtures of laboratory synthesized phosgene with X (X = Cl2, Br2) trapped in argon matrices.

引用

页码：335 / 345

页数：11

共 23 条

[1] PHOTOCHEMISTRY OF AN OZONE-BROMINE COMPLEX - THE IR-SPECTRUM OF MATRIX-ISOLATED BR2O [J].