A STEREOSELECTIVE ROUTE TO THE SUGAR-CINNAMATE UNIT OF HYGROMYCIN-A

被引：19

作者：

BUCHANAN, JG

HILL, DG

WIGHTMAN, RH

BODDY, IK

HEWITT, BD

机构：

[1] HERIOT WATT UNIV,DEPT CHEM,EDINBURGH EH14 4AS,MIDLOTHIAN,SCOTLAND

[2] AGREVO UK LTD,SAFFRON WALDEN CB10 1XL,ESSEX,ENGLAND

来源：

TETRAHEDRON | 1995年 / 51卷 / 21期

关键词：

D O I：

10.1016/0040-4020(95)00262-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Various aryl 6-deoxy-5-keto-beta-D-arabino-hexofuranosides including one (42) corresponding to the sugar-cinnamate unit of Hygromycin A (1) have been synthesized by a method in which 6-deoxy-beta-D-glucofuranosides are first prepared, followed by configurational inversion at positions 2 and 3 via 23-anhydro-6-deoxy-beta-D-mamofuranosyl intermediates.

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页码：6033 / 6050

页数：18

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