OHMIC DROP AND ZONES OF REDUCED OVERPOTENTIAL DURING THE GROWTH OF SMALL CLUSTERS

被引：20

作者：

MILCHEV, A

机构：

[1] Institute of Physical Chemistry, Bulgarian Academy of Sciences, Sofia

来源：

JOURNAL OF APPLIED ELECTROCHEMISTRY | 1990年 / 20卷 / 02期

关键词：

D O I：

10.1007/BF01033610

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The electrochemical growth of small clusters at constant external voltage has been studied theoretically. Expressions are derived here for the time dependence of the cluster size and the growth current accounting for the ohmic drop in the electrolyte. The potential distribution around the growing clusters is determined and the kinetics of spread of the zones of reduced overpotential are investigated. © 1990 Chapman and Hall Ltd.

引用

页码：307 / 318

页数：12

共 30 条

[1] FORMULATION OF CURRENT-TIME TRANSIENTS DUE TO NUCLEATION AND COALESCENCE OF SPHERICAL-CAP GROWTH FORMS [J].

ABYANEH, MY .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1986, 209 (01) :1-10

[2] ELECTROCRYSTALLIZATION OF MERCURY SILVER AND PALLADIUM [J].

ASTLEY, DJ ;

HARRISON, JA ;

THIRSK, HR .

TRANSACTIONS OF THE FARADAY SOCIETY, 1968, 64 (541P) :192-&

[3]

BARABOSHKIN AN, 1965, T I ELEKTROKHIM AKAD, V7, P47

[4]

BOSKO E, 1982, J ELECTROANAL CHEM, V134, P213

[5]

BOSTANOV V, 1969, IZV OTDNIYA KHIM NAU, V2, P885

[6] NUCLEATION ON ACTIVE-SITES .4. INVENTION OF AN ELECTRONIC METHOD OF COUNTING THE NUMBER OF CRYSTALS AS A FUNCTION OF TIME - AND THE DISCOVERY OF NUCLEATION RATE DISPERSION [J].

DEUTSCHER, RL ;

FLETCHER, S .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1988, 239 (1-2) :17-54

[7]

FLEISCHMANN M, 1963, ADV ELECTROCHEMISTRY, V3, pCH3

[8] ELECTROCHEMICAL DEPOSITION OF HEMISPHERICAL NUCLEI UNDER DIFFUSION CONTROL - SOME THEORETICAL CONSIDERATIONS [J].

FLETCHER, S .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1983, 79 :467-479

[9]

GERISCHER H, 1951, Z ELEKTROCHEM, V55, P98

[10]

GERISCHER H, 1957, Z ELEKTROCHEM, V61, P1159

← 1 2 3 →