ENZYMATIC HETEROATOM CHEMISTRY .1. ENZYMATIC RESOLUTION OF RACEMIC PHOSPHINOYLACETATES HAVING A STEREOGENIC PHOSPHORUS ATOM

被引：23

作者：

KIELBASINSKI, P ^{[1
]}

ZURAWINSKI, R ^{[1
]}

PIETRUSIEWICZ, KM ^{[1
]}

ZABLOCKA, M ^{[1
]}

MIKOLAJCZYK, M ^{[1
]}

机构：

[1] POLISH ACAD SCI,CTR MOLEC & MACROMOLEC STUDIES,PL-90363 LODZ,POLAND

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 38期

关键词：

D O I：

10.1016/0040-4039(94)88231-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A series of racemic methyl alkylphenylphosphinoylacetates was hydrolyzed in the presence of pig liver esterase (PLE) to give the corresponding P-chiral phosphinoylacetic acids and unreacted esters in a high enantiomeric purity (72-100% ee).

引用

页码：7081 / 7084

页数：4

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