A CONTRIBUTION TO THE SILICENIUM ION DEBATE

被引:35
作者
EABORN, C
机构
[1] School of Chemistry and Molecular Sciences, University of Sussex, Brighton
关键词
D O I
10.1016/0022-328X(91)86269-V
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
It is suggested that the fact that (Me3Si)3CSiMe2OClO3 undergoes solvolysis fairly slowly in MeOH, and very slowly, if at all, in CF3CH2OH, argues strongly against the view that triorganosilyl perchlorates are significantly ionized in dichloromethane or sulpholane. Brief comments are made on aspects of some reactions that may involve silicenium ions as intermediates in solution.
引用
收藏
页码:173 / 177
页数:5
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