NOVEL COLUMNAR LIQUID-CRYSTALS DESIGNED FROM CONE-SHAPED CALIX[4]ARENES - THE RIGID BOWL IS ESSENTIAL FOR THE FORMATION OF THE LIQUID-CRYSTAL PHASE

被引：56

作者：

KOMORI, T ^{[1
]}

SHINKAI, S ^{[1
]}

机构：

[1] ERATO, RES DEV CORP JAPAN, CHEMIRECOGN PROJECT, 2432-3 AIKAWA, KURUME, FUKUOKA 830, JAPAN

来源：

CHEMISTRY LETTERS | 1993年 / 08期

关键词：

D O I：

10.1246/cl.1993.1455

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Conformationally-immobile calix[4]arenes with a cone conformation coupled to C6H4-p-C(m)H2m+l (m=3, 8, 12, 14, and 16) via an azomethine linkage were synthesized. It was found that the compounds with m greater-than-or-equal-to 8 have the liquid crystal phase with a columnar arrangement.

引用

页码：1455 / 1458

页数：4

共 12 条

[1] LIQUID-CRYSTALLINE SOLVENTS AS MECHANISTIC PROBES .12. SOLVENT ANISOTROPY EFFECTS ON THE BENDING OF HYDROCARBON CHAINS IN ALPHA,OMEGA-BIS(1-PYRENYL)ALKANES
ANDERSON, VC
WEISS, RG
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (22) : 6628 - 6637
[2] ASYMMETRIC INDUCTION IN CHOLESTERIC MEDIA REVISITED
ESKENAZI, C
NICOUD, JF
KAGAN, HB
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1979, 44 (06) : 995 - 999
[3] CONFORMATIONS AND STRUCTURES OF TETRA-O-ALKYL-PARA-TERT-BUTYLCALIX[4]ARENES - HOW IS THE CONFORMATION OF CALIX[4]ARENES IMMOBILIZED
IWAMOTO, K
ARAKI, K
SHINKAI, S
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1991, 56 (16) : 4955 - 4962
[4] A NEW CLASS OF MESOMORPHIC MATERIALS DESIGNED FROM CALIX[N]ARENES
KOMORI, T
SHINKAI, S
[J]. CHEMISTRY LETTERS, 1992, (06) : 901 - 904
[5] TUBULAR MESOPHASES - LIQUID-CRYSTALS CONSISTING OF MACROCYCLIC MOLECULES
LEHN, JM
MALTHETE, J
LEVELUT, AM
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1985, (24) : 1794 - 1796
[6] ORGANIC-REACTIONS IN LIQUID-CRYSTALLINE SOLVENTS .6. REGIOCHEMICAL CONTROL OF BIMOLECULAR CHEMICAL-REACTIVITY IN SMECTIC AND CHOLESTERIC LIQUID-CRYSTALS
LEIGH, WJ
MITCHELL, DS
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (04) : 1311 - 1313
[7] INVERSION OF THE CYCLOTRIBENZYLENE CONE IN A COLUMNAR MESOPHASE - A POTENTIAL WAY TO FERROELECTRIC MATERIALS
MALTHETE, J
COLLET, A
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (24) : 7544 - 7545
[8] TUBULAR MESOPHASES - A STRUCTURAL-ANALYSIS
MALTHETE, J
LEVELUT, AM
LEHN, JM
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (19) : 1434 - 1436
[9] THERMOCONTROL OF ION PERMEATION THROUGH TERNARY COMPOSITE MEMBRANES COMPOSED OF POLYMER LIQUID-CRYSTAL AMPHIPHILIC CROWN ETHERS
SHINKAI, S
NAKAMURA, S
TACHIKI, S
MANABE, O
KAJIYAMA, T
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (11) : 3363 - 3365
[10] RIGID BOWLIC LIQUID-CRYSTALS BASED ON TUNGSTEN OXO CALIX[4]ARENES - HOST GUEST EFFECTS AND HEAD-TO-TAIL ORGANIZATION
XU, B
SWAGER, TM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (03) : 1159 - 1160

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