REACTIVE SCATTERING OF O(D-1)+HD - PRODUCT SPEED AND ANGLE DISTRIBUTIONS

被引：80

作者：

CHE, DC

LIU, KP

机构：

[1] Institute of Atomic and Molecular Sciences, Academia Sinica, Taipei, 10764

来源：

JOURNAL OF CHEMICAL PHYSICS | 1995年 / 103卷 / 12期

关键词：

D O I：

10.1063/1.470606

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The reaction dynamics of O(D-1)+HD --> OH+D and OD+H was investigated at a collision energy of 4.55 kcal/mole in a dressed-beam apparatus. The speed and angle distributions of H(D) products were interrogated using Doppler-shift measurements in a (1+1) REMPI (resonantly enhanced multiphoton ionization) detection scheme.: Both product channels exhibited marked forward-backward asymmetry in the angular distributions and the translational energy release to the OD+H channel was substantially larger, about 1.4 on the average, than that to the OH+D product. (C) 1995 American Institute of Physics.

引用

收藏

页码：5164 / 5167

页数：4

相关论文

共 31 条

[1] A REDUCED DIMENSIONALITY QUANTUM REACTIVE SCATTERING STUDY OF THE INSERTION REACTION O(1D)+H-2-]OH+H [J].

BADENHOOP, JK ;

KOIZUMI, H ;

SCHATZ, GC .

JOURNAL OF CHEMICAL PHYSICS, 1989, 91 (01) :142-149

[2] REACTIVE SCATTERING OF O(1D)+H2 [J].

BUSS, RJ ;

CASAVECCHIA, P ;

HIROOKA, T ;

SIBENER, SJ ;

LEE, YT .

CHEMICAL PHYSICS LETTERS, 1981, 82 (03) :386-391

[3] VIBRATIONAL-EXCITATION OF OH(X2-PI) PRODUCED IN THE REACTION OF O(D-1) WITH H-2 [J].

BUTLER, JE ;

MACDONALD, RG ;

DONALDSON, DJ ;

SLOAN, JJ .

CHEMICAL PHYSICS LETTERS, 1983, 95 (03) :183-188

[4] REACTION DYNAMICS OF O(1D2) + H-2, HD, D2-OH, OD(X2PI-I) PRODUCT INTERNAL ENERGY-DISTRIBUTIONS [J].

BUTLER, JE ;

JURSICH, GM ;

WATSON, IA ;

WIESENFELD, JR .

JOURNAL OF CHEMICAL PHYSICS, 1986, 84 (10) :5365-5377

[5]

CHE DC, UNPUB

[6] QUASICLASSICAL DYNAMICAL STUDY OF THE REACTION O(1D)+HD(1-SIGMA-+)-]OD/OH(2-PI)+H/D(2S) ON A 2-VALUED POTENTIAL-ENERGY SURFACE [J].

DUNNE, LJ .

CHEMICAL PHYSICS LETTERS, 1989, 158 (06) :535-539

[7] A THEORETICAL-STUDY OF COMPLEX-FORMATION, ISOTOPE EFFECTS, AND ENERGY PARTITIONING IN THE O(1D)+H-2(D2,HD) REACTION [J].

FITZCHARLES, MS ;

SCHATZ, GC .

JOURNAL OF PHYSICAL CHEMISTRY, 1986, 90 (16) :3634-3644

[8] ENHANCED PRODUCTION OF TUNABLE VUV RADIATION BY PHASE-MATCHED FREQUENCY TRIPLING IN KRYPTON AND XENON [J].

HILBIG, R ;

WALLENSTEIN, R .

IEEE JOURNAL OF QUANTUM ELECTRONICS, 1981, 17 (08) :1566-1573

[9] THE NASCENT PRODUCT VIBRATIONAL-ENERGY DISTRIBUTION OF THE REACTION O(1D)+H-2 BY THE GRATING SELECTION CHEMICAL-LASER TECHNIQUE [J].

HUANG, YL ;

GU, YK ;

LIU, CS ;

YANG, XF ;

TAO, YS .

CHEMICAL PHYSICS LETTERS, 1986, 127 (05) :432-437

[10]

John Lee Y., COMMUNICATION

← 1 2 3 4 →