FUNCTIONAL POLYTHIIRANES .2. POLYMERS OF METHYL (2,3-EPITHIOPROPYL-THIO) ETHANOATE

被引：12

作者：

BONNANSPLAISANCE, C ^{[1
]}

COURRIC, S ^{[1
]}

LEVESQUE, G ^{[1
]}

机构：

[1] UNIV CAEN,CHIM POLYMERES & INTERFACES LAB,CNRS,UA 480,F-14050 CAEN,FRANCE

来源：

POLYMER BULLETIN | 1992年 / 28卷 / 05期

关键词：

D O I：

10.1007/BF00296037

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The synthesis of a new monomer holding a carboxylate function and a thiirane ring, is described in this study. Its homopolymerization through thiirane ring opening, using as initiator, tetramethylammonium (di)thiobenzoate in DMF and affording polysulfides with pendent carboxylate groups is investigated. The copolymers with methyl thiirane are identified by 13C NMR spectroscopy. The corresponding polyacids can be easily obtained through saponification.

引用

页码：489 / 495

页数：7

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