ISOLATION, STRUCTURAL CHARACTERIZATION, AND DIOXYGEN REACTIVITY OF THE HETEROBIMETALLIC COMPLEX [OS(N)(CH2SIME3)2(OCRO3)(DPPE)]-

被引：9

作者：

ALLEN, JL ^{[1
]}

SHAPLEY, PA ^{[1
]}

WILSON, SR ^{[1
]}

机构：

[1] UNIV ILLINOIS,DEPT CHEM,URBANA,IL 61801

来源：

ORGANOMETALLICS | 1994年 / 13卷 / 10期

关键词：

D O I：

10.1021/om00022a001

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The heterobimetallic complex [Y][Os(N)(CH2-SiMe3)2(mu-O)2CrO2], 1 (Y = [PPh4], [N(n-Bu)4]), reacts with Ph2PCH2CH2PPh2 (dppe) to form [Y][Os(N)(CH2-SiMe3)2(dppe)(OCrO3)], 2. The structure of 2 was determined by X-ray diffraction. Complex 1 is a catalyst for the oxidation of dppe to Ph2P(O)CH2CH2P(O)Ph2 with molecular oxygen.

引用

页码：3749 / 3751

页数：3

共 27 条

[1] THE SELECTIVE OXIDATION OF PRIMARY ALCOHOLS TO ALDEHYDES BY O-2 EMPLOYING A TRINUCLEAR RUTHENIUM CARBOXYLATE CATALYST
BILGRIEN, C
DAVIS, S
DRAGO, RS
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (12) : 3786 - 3787
[2] RHENIUM(V) OXIDE COMPLEXES - CRYSTAL AND MOLECULAR-STRUCTURES OF REOI2(PPH3)2(OREO3) AND OF REOI2(PPH3)(OPPH3)(OREO3).0.5C6H6 OBTAINED FROM THE REACTION OF REO2I(PPH3)2 WITH OXYGEN
CIANI, G
SIRONI, A
BERINGHELLI, T
DALFONSO, G
FRENI, M
[J]. INORGANICA CHIMICA ACTA, 1986, 113 (01) : 61 - 65
[3] COTTON FA, 1980, ADV INORG CHEM RAD, P170
[4] KINETICS AND MECHANISM OF THE OXYGENATION OF TRIPHENYLPHOSPHINE BY BIS(ETHYL-L-CYSTEINATO)DIOXOMOLYBDENUM(VI)
DELI, J
SPEIER, G
[J]. TRANSITION METAL CHEMISTRY, 1981, 6 (04) : 227 - 229
[5] MECHANISM OF CIS-DIRECTED 4-ELECTRON OXIDATION BY A TRANS-DIOXO COMPLEX OF RUTHENIUM(VI)
DOVLETOGLOU, A
MEYER, TJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (01) : 215 - 223
[6] CONTROLLED REACTION OF MOLECULAR-OXYGEN WITH [MNI2(PPH2ME)2] TO FORM THE MIXED PHOSPHINE PHOSPHINE OXIDE COMPLEX [MNI2(OPPH2ME)(PPH2ME)] AND THE BIS(PHOSPHINE OXIDE) COMPLEX [MNI2(OPPH2ME)2]
GODFREY, SM
MCAULIFFE, CA
NDIFON, PT
PRITCHARD, RG
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (22): : 3373 - 3377
[7] MECHANISTICS STUDIES ON THE COBALT(II) SCHIFF-BASE CATALYZED OXIDATION OF OLEFINS BY O-2
HAMILTON, DE
DRAGO, RS
ZOMBECK, A
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (02) : 374 - 379
[8] OXYGEN ACTIVATION BY TRANSITION-METAL COMPLEXES .2. BIS(ACETYLACETONATO)COBALT(II)-CATALYZED OXIDATION OF TRIBUTYLPHOSPHINE
HANZLIK, RP
WILLIAMSON, D
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (21) : 6570 - 6573
[9] MULTIPLE BONDS BETWEEN MAIN-GROUP ELEMENTS AND TRANSITION-METALS .50. METHYLRHENIUM OXIDES - SYNTHESIS FROM R2O7 AND CATALYTIC ACTIVITY IN OLEFIN METATHESIS
HERRMANN, WA
KUCHLER, JG
FELIXBERGER, JK
HERDTWECK, E
WAGNER, W
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1988, 27 (03): : 394 - 396
[10] MULTIPLE BONDS BETWEEN MAIN GROUP ELEMENTS AND TRANSITION-METALS .8. CHEMISTRY OF THE NOVEL OXO HALF-SANDWICH COMPLEX (ETA-5-C5ME5)REO3 - FUNCTIONALIZATION AND AGGREGATION
HERRMANN, WA
SERRANO, R
KUSTHARDT, U
ZIEGLER, ML
GUGGOLZ, E
ZAHN, T
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1984, 23 (07): : 515 - 517

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