INVESTIGATION OF A NICKEL-OXIDE SYSTEM FOR HETEROGENEOUS OXIDATION OF ORGANIC-COMPOUNDS

被引：61

作者：

CHRISTOSKOVA, SG ^{[1
]}

DANOVA, N ^{[1
]}

GEORGIEVA, M ^{[1
]}

ARGIROV, OK ^{[1
]}

MEHANDZHIEV, D ^{[1
]}

机构：

[1] BULGARIAN ACAD SCI,INST GEN & INORGAN CHEM,BU-1040 SOFIA,BULGARIA

来源：

APPLIED CATALYSIS A-GENERAL | 1995年 / 128卷 / 02期

关键词：

CATALYST CHARACTERIZATION (ESR IR XPS); NICKEL OXIDE; OXIDATION; REACTION MECHANISM;

D O I：

10.1016/0926-860X(95)00013-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The structure of a nickel oxide system, which is an efficient oxidant for organic compounds, has been studied by spectroscopic methods such as IR, X-ray photoelectron spectroscopy, electron spin resonance, X-ray spectroscopy as well as by thermal and chemical analyses. It has been clearly shown that the reagent is not a peroxide, but a higher nickel oxide. An oxidation reaction mechanism of organic compounds has been proposed.

引用

页码：219 / 229

页数：11

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