THE FIRST SOLID-STATE STRUCTURE OF A MIXED-ANION ROLI/LIOH COMPOUND - ((T)BUOLI)(10)CENTER-DOT(LIOH)(6)

被引：31

作者：

LAMBERT, C ^{[1
]}

HAMPEL, F ^{[1
]}

SCHLEYER, PV ^{[1
]}

DAVIDSON, MG ^{[1
]}

SNAITH, R ^{[1
]}

机构：

[1] UNIV CAMBRIDGE,CHEM LAB,CAMBRIDGE CB2 1EW,ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 487卷 / 1-2期

关键词：

LITHIUM; ALKOXIDE; HYDROXIDE; MIXED ANION AGGREGATE; X-RAY DIFFRACTION;

D O I：

10.1016/0022-328X(94)05090-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

X-Ray analysis of the title compound ((t)BuOLi)(10).(LiOH)(6) (1) which was obtained by prolonged exposure of a concentrated (t)BuOLi/hexane solution to moist air, has revealed a mixed-anion aggregate structure comprised of two hexagonal ((t)BuO)(5)(OH)Li-6 subaggregates and a crossed LiOH ladder structure.

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页码：139 / 141

页数：3

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