A NOVEL SYNTHESIS OF INTERNAL ALKENYLDIALKYLBORANE BY THE REACTION OF 1-HALO-1-ALKENYLDIALKYLBORANE WITH GRIGNARD-REAGENT

被引：19

作者：

ARASE, A

HOSHI, M

MASUDA, Y

机构：

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1984年 / 57卷 / 01期

关键词：

D O I：

10.1246/bcsj.57.209

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

To synthesize internal alkenyldialkylboranes, coupling reactions were carried out by using 1-halo-1-alkenyldialkylboranes and Grignard reagents. Hydrogen peroxide oxidation and protonolysis with acetic acid of the reaction product revealed that internal (E)-alkenyldialkylborane was formed in 60-90% yield.

引用

页码：209 / 213

页数：5

共 22 条

[1]

Brown H C., 1962, HYDROBORATION

[2]

BROWN HC, 1982, SYNTHESIS-STUTTGART, P195

[3] ORGANOBORANES .23. REACTION OF ORGANOLITHIUM AND GRIGNARD-REAGENTS WITH ALPHA-BROMOALKYLBORONATE ESTERS - CONVENIENT, ESSENTIALLY QUANTITATIVE PROCEDURE FOR SYNTHESIS OF TERTIARY ALKYLBORANES, BENZYLBORANES, PROPARGYLBORANES, AND STEREOSPECIFIC ALLYLBORANES [J].