USING THERMOANALYTICAL DATA .1. THE POWER OF KINETIC-PARAMETERS DETERMINED FROM THERMOGRAVIMETRY TO DESCRIBE THE EXPERIMENTAL BEHAVIOR OF THE SAMPLE

被引：12

作者：

CEIPIDOR, UB

BUCCI, R

CARUNCHIO, V

MAGRI, AD

机构：

[1] UNIV LA SAPIENZA,DIPARTIMENTO CHIM,P A MORO,I-00185 ROME,ITALY

[2] UNIV BASILICATA,IST CHIM,I-85100 POTENZA,ITALY

来源：

THERMOCHIMICA ACTA | 1990年 / 158卷 / 01期

关键词：

D O I：

10.1016/0040-6031(90)80060-C

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Sources of misunderstandings when evaluating kinetic parameters from thermogravimetric (TG) curves are discussed. A simple method for calculating Arrhenius parameters, suitable for implementation on a PC connected to the TG apparatus, is presented. The results obtained with calcium oxalate are discussed with respect to their ability to predict thermal behaviour in several experimental conditions: agreement with experimental data is satisfactory. This is not so when using some literature-cited kinetic parameters, which fail to represent the same TG curves from which they are extracted. Suggestions are derived for design of a modern TG apparatus connected to a PC. © 1990.

引用

页码：125 / 141

页数：17

共 17 条

[1] CEIPIDOR UB, 1989, IN PRESS J THERM ANA, V35
[2] KINETIC-ANALYSIS OF THERMAL-DECOMPOSITION REACTIONS .1. THERMAL-DECOMPOSITION OF POTASSIUM BROMATE
DIEFALLAH, EM
BASAHL, SN
OBAID, AY
ABUEITTAH, RH
[J]. THERMOCHIMICA ACTA, 1987, 111 : 49 - 56
[3] THE APPLICATION OF THERMOANALYTICAL TECHNIQUES TO REACTION KINETICS - THE THERMOGRAVIMETRIC EVALUATION OF THE KINETICS OF THE DECOMPOSITION OF CALCIUM OXALATE MONOHYDRATE
FREEMAN, ES
CARROLL, B
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1958, 62 (04) : 394 - 397
[4] KINETICS OF DECOMPOSITION OF THE SOLID-STATE - IS THERE REALLY A DICHOTOMY
GARN, PD
[J]. THERMOCHIMICA ACTA, 1988, 135 : 71 - 77
[5] A MODEL FOR THE THERMAL RESPONSE OF POLYMER COMPOSITE-MATERIALS WITH EXPERIMENTAL-VERIFICATION
HENDERSON, JB
WIEBELT, JA
TANT, MR
[J]. JOURNAL OF COMPOSITE MATERIALS, 1985, 19 (06) : 579 - 595
[6] A MATHEMATICAL-MODEL TO PREDICT THE THERMAL RESPONSE OF DECOMPOSING, EXPANDING POLYMER COMPOSITES
HENDERSON, JB
WIECEK, TE
[J]. JOURNAL OF COMPOSITE MATERIALS, 1987, 21 (04) : 373 - 393
[7] JINXIANG L, 1983, ACTA CHIM SINICA, V41, P169
[8] QUANQIN Z, 1988, THERMOCHIM ACTA, V135, P187
[9] COMPUTER-DETERMINED KINETIC-PARAMETERS FROM TG CURVES .18.
REICH, L
POLLARA, LZ
STIVALA, SS
[J]. THERMOCHIMICA ACTA, 1987, 111 : 379 - 382
[10] COMPARISON OF ISOTHERMAL AND NONISOTHERMAL TG-DATA KINETIC-ANALYSIS OF CALCIUM-OXALATE DEHYDRATION
SALVADOR, AR
CALVO, EG
[J]. THERMOCHIMICA ACTA, 1986, 107 : 283 - 290

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