INFLUENCE OF MAGNESIUM-ALUMINUM SPINEL ON THE DIRECTED OXIDATION OF MOLTEN ALUMINUM-ALLOYS

被引:75
作者
SINDEL, M
TRAVITZKY, NA
CLAUSSEN, N
机构
[1] Advanced Ceramics Group, Technische Universität Hamburg-Harburg, Hamburg
关键词
alloys; aluminum; magnesium; oxidation; spinels;
D O I
10.1111/j.1151-2916.1990.tb06736.x
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The directed oxidation of some molten aluminum alloys was studied. Alloys containing Si, Zn, and Mg are readily converted into Al2O3/Al composites with the characteristic directed metal oxidation process (DIMOX) metal‐channel structure. No reaction took place when alloys without Mg were used. However, when Mg‐free melts containing Si and Zn were in contact with bulk spinel (MgAl2O4), the typical reaction product grew from the metal pool, although without formation of the spinel starter layer which was thought to be a prerequisite for DIMOX growth. Furthermore, the growth front was more planar than when Mg‐containing alloys were used. Copyright © 1990, Wiley Blackwell. All rights reserved
引用
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页码:2615 / 2618
页数:4
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