COMPETITION RATE CONSTANTS FOR ADDITION OF CYCLOHEXYL RADICAL TO AMIDE SUBSTITUTED ALKENES - ORIGINS OF ACYCLIC STEREOSELECTION IN RADICAL ADDITIONS

被引：27

作者：

PORTER, NA

WU, WX

MCPHAIL, AT

机构：

[1] Department of Chemistry Paul M. Gross Chemical Laboratory Duke University Durham

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 06期

关键词：

D O I：

10.1016/S0040-4039(00)74863-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Competition rate constants were determined for the addition of cyclohexyl radical to alpha,beta unsaturated amides derived from pyrrolidine and trans-2,5-dimethylpyrrolidine. The relative rates can be understood by single crystal X-Ray analyses of the alkenes and an examination of the presumed transition state

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页码：707 / 710

页数：4

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