ELECTROLYTIC PARTIAL FLUORINATION OF ORGANIC-COMPOUNDS .14. ELECTROCHEMISTRY OF HYPERVALENT COMPOUNDS .2. THE FIRST ELECTROSYNTHESIS OF HYPERVALENT IODOBENZENE DIFLUORIDE DERIVATIVES AND ITS APPLICATION TO INDIRECT ANODIC GEM-DIFLUORINATION

被引：137

作者：

FUCHIGAMI, T

FUJITA, T

机构：

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1994年 / 59卷 / 24期

关键词：

D O I：

10.1021/jo00103a003

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The electrosynthesis of hypervalent iodobenzene difluorides was accomplished by anodic oxidation of p-nitro- and p-methoxyiodobenzenes with Et(3)N.3HF in anhydrous acetonitrile, and p-methoxyiodobenzene difluoride was used as a mediator for indirect anodic gem-difluorination of dithioketals.

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页码：7190 / 7192

页数：3

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